Flights from Brussels to other cities in Europe leave from Charleroi Airport, not the main International Airport. To get to Charleroi, there is a shuttle bus from the Brussels Midi (also known as Brussels Zuid). I had a heck of a time finding the shuttle. I finally asked the information booth which helped somewhat. Go out the left end of the station (when facing away from the tracks). Once outside, go left and at the side of the station, you’ll see several busses lined up. I just asked until I found it. I attached a picture of what mine looked like. It was 13 Euros and bring exact change to pay the driver. I think you can also order tickets online. It leaves every half hour starting at 10 after the hour.

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